On the Adam-Gibbs-Wolynes scenario for the viscosity increase in glasses

We reformulate the interpretation of the mean-field glass transition scenario for finite dimensional systems, proposed by Wolynes and collaborators. This allows us to establish clearly a temperature dependent length xi* above which the mean-field glass transition picture has to be modified. We argue in favor of the mosaic state introduced by Wolynes and collaborators, which leads to the Adam-Gibbs relation between the viscosity and configurational entropy of glass forming liquids. Our argument is a mixture of thermodynamics and kinetics, partly inspired by the Random Energy Model: small clusters of particles are thermodynamically frozen in low energy states, whereas large clusters are kinetically frozen by large activation energies. The relevant relaxation time is that of the smallest `liquid' clusters. Some physical consequences are discussed.Comment: 8 page

Anomalous dynamical light scattering in soft glassy gels

We compute the dynamical structure factor S(q,tau) of an elastic medium where force dipoles appear at random in space and in time, due to `micro-collapses' of the structure. Various regimes are found, depending on the wave vector q and the collapse time. In an early time regime, the logarithm of the structure factor behaves as (q tau)^{3/2}, as predicted by Cipelletti et al. [1] using heuristic arguments. However, in an intermediate time regime we rather obtain a q tau)^{5/4} behaviour. Finally, the asymptotic long time regime is found to behave as q^{3/2} tau. We also give a plausible scenario for aging, in terms of a strain dependent energy barrier for micro-collapses. The relaxation time is found to grow with the age t_w, quasi-exponentially at first, and then as t_w^{4/5} with logarithmic corrections.Comment: 15 pages, 1 .eps figure. Submitted to EPJ-

Numerical study of the temperature and porosity effects on the fracture propagation in a 2D network of elastic bonds

This article reports results concerning the fracture of a 2d triangular lattice of atoms linked by springs. The lattice is submitted to controlled strain tests and the influence of both porosity and temperature on failure is investigated. The porosity is found on one hand to decrease the stiffness of the material but on the other hand it increases the deformation sustained prior to failure. Temperature is shown to control the ductility due to the presence of cavities that grow and merge. The rough surfaces resulting from the propagation of the crack exhibit self-affine properties with a roughness exponent $\zeta = 0.59 \pm 0.07$ over a range of length scales which increases with temperature. Large cavities also have rough walls which are found to be fractal with a dimension, $D$, which evolves with the distance from the crack tip. For large distances, $D$ is found to be close to 1.5, and close to 1.0 for cavities just before their coalescence with the main crack

Glassy effects in the swelling/collapse dynamics of homogeneous polymers

We investigate, using numerical simulations and analytical arguments, a simple one dimensional model for the swelling or the collapse of a closed polymer chain of size N, representing the dynamical evolution of a polymer in a \Theta-solvent that is rapidly changed into a good solvent (swelling) or a bad solvent (collapse). In the case of swelling, the density profile for intermediate times is parabolic and expands in space as t^{1/3}, as predicted by a Flory-like continuum theory. The dynamics slows down after a time \propto N^2 when the chain becomes stretched, and the polymer gets stuck in metastable `zig-zag' configurations, from which it escapes through thermal activation. The size of the polymer in the final stages is found to grow as \sqrt{\ln t}. In the case of collapse, the chain very quickly (after a time of order unity) breaks up into clusters of monomers (`pearls'). The evolution of the chain then proceeds through a slow growth of the size of these metastable clusters, again evolving as the logarithm of time. We enumerate the total number of metastable states as a function of the extension of the chain, and deduce from this computation that the radius of the chain should decrease as 1/\ln(\ln t). We compute the total number of metastable states with a given value of the energy, and find that the complexity is non zero for arbitrary low energies. We also obtain the distribution of cluster sizes, that we compare to simple `cut-in-two' coalescence models. Finally, we determine the aging properties of the dynamical structure. The subaging behaviour that we find is attributed to the tail of the distribution at small cluster sizes, corresponding to anomalously `fast' clusters (as compared to the average). We argue that this mechanism for subaging might hold in other slowly coarsening systems.Comment: 35 pages, 12 .ps figures. Submitted to EPJ

Can crack front waves explain the roughness of cracks ?

We review recent theoretical progress on the dynamics of brittle crack fronts and its relationship to the roughness of fracture surfaces. We discuss the possibility that the intermediate scale roughness of cracks, which is characterized by a roughness exponent approximately equal to 0.5, could be caused by the generation, during local instabilities by depinning, of diffusively broadened corrugation waves, which have recently been observed to propagate elastically along moving crack fronts. We find that the theory agrees plausibly with the orders of magnitude observed. Various consequences and limitations, as well as alternative explanations, are discussed. We argue that another mechanism, possibly related to damage cavity coalescence, is needed to account for the observed large scale roughness of cracks that is characterized by a roughness exponent approximately equal to 0.8Comment: 26 pages, 3 .eps figure. Submitted to J. Mech. Phys. Solid

Evidence of Deep Water Penetration in Silica during Stress Corrosion Fracture

We measure the thickness of the heavy water layer trapped under the stress corrosion fracture surface of silica using neutron reflectivity experiments. We show that the penetration depth is 65–85 Å, suggesting the presence of a damaged zone of ~100 Å extending ahead of the crack tip during its propagation. This estimate of the size of the damaged zone is compatible with other recent results

Linear and non linear response in the aging regime of the 1D trap model

We investigate the behaviour of the response function in the one dimensional trap model using scaling arguments that we confirm by numerical simulations. We study the average position of the random walk at time tw+t given that a small bias h is applied at time tw. Several scaling regimes are found, depending on the relative values of t, tw and h. Comparison with the diffusive motion in the absence of bias allows us to show that the fluctuation dissipation relation is, in this case, valid even in the aging regime.Comment: 5 pages, 3 figures, 3 references adde

Rejuvenation in the Random Energy Model

We show that the Random Energy Model has interesting rejuvenation properties in its frozen phase. Different `susceptibilities' to temperature changes, for the free-energy and for other (`magnetic') observables, can be computed exactly. These susceptibilities diverge at the transition temperature, as (1-T/T_c)^-3 for the free-energy.Comment: 9 pages, 1 eps figur

Multiple scaling regimes in simple aging models

We investigate aging in glassy systems based on a simple model, where a point in configuration space performs thermally activated jumps between the minima of a random energy landscape. The model allows us to show explicitly a subaging behavior and multiple scaling regimes for the correlation function. Both the exponents characterizing the scaling of the different relaxation times with the waiting time and those characterizing the asymptotic decay of the scaling functions are obtained analytically by invoking a `partial equilibrium' concept.Comment: 4 pages, 3 figure